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WebAug 25, 2014 · A novel procedure for the synthesis of C2-diversified oxazoles, through palladium-catalyzed imidoylative cyclization of α-isocyanoacetamides with aryl, vinyl, alkynyl halides, or triflates, was developed. Migratory insertion of isocyanide into a Csp3-palladium(II) intermediate in a cascade process was also realized, generating alkyl ... WebAug 5, 2014 · Therefore, oxazoles functionalized at the C2 position with sp, sp 2, and sp 3 hybridized carbon atoms are accessible by applying this method. Abstract A novel procedure for the synthesis of C2-diversified oxazoles, through palladium-catalyzed imidoylative cyclization of α-isocyanoacetamides with aryl, vinyl, alkynyl halides, or triflates, was ... http://www.cba.uc.edu/profiles/documents/kerimj/pci/kerimj-1.pdf fred white ladac